Oxidative Palladium(II)-Catalyzed Carbocyclization
Control of Alkene Geometry or Relative Configuration
Paperback
Lieferzeit: Print on Demand - Lieferbar innerhalb von 3-5 Werktagen I
ISBN-13:
9783848498802
Veröffentl:
2013
Einband:
Paperback
Erscheinungsdatum:
14.08.2013
Seiten:
280
Autor:
Sandeep Reddy Kandukuri
Gewicht:
435 g
Format:
220x150x17 mm
Sprache:
Englisch
Beschreibung:
The present work is dedicated to the development and application of oxidative palladium(II)-catalyzed carbocyclizations. A general procedure for an aerobic palladium(II)-catalyzed endo cyclization of indole derivatives is presented. Further application of this new methodology in the synthesis of C-2 alkenylated indoles in diastereomerically pure form is also reported. The other methodologies involves hydroxy-directed diastereotopic group selection of prochiral bis(homoallylic) alcohols and enantioselective Fujiwara Moritani cyclizations. In addition to this, the book also details on the indole directed aerobic dehydrogenation of cyclohexenes.