Science of Synthesis: Cross Coupling and Heck-Type Reactions

In "Science of Synthesis: Cross Coupling and Heck-Type Reactions", expert authors present and discuss the best and most reliable methods currently available for the formation of new carbon-carbon and carbon-heteroatom bonds using these reactions, highlighted with experimental procedures. The three volumes provide an extensive overview of the current state of the art in this field of central importance in modern chemistry, and are an invaluable resource for synthetic organic chemists. This volume covers carbon-carbon bond formation. Virtually all of the chemistry described has achieved "Name Reaction" stature and the chapters are organized accordingly. Suzuki-Miyaura reactions, Hiyama cross coupling, Stille coupling, Negishi coupling, and finally Kumada coupling are discussed in sequence, with a particular emphasis on breadth of scope rather than detailed minutiae. // The content of this e-book was originally published in October 2012.

In "Science of Synthesis: Cross Coupling and Heck-Type Reactions", expert authors present and discuss the best and most reliable methods currently available for the formation of new carbon-carbon and carbon-heteroatom bonds using these reactions, highlighted with experimental procedures. The three volumes provide an extensive overview of the ...

<p>1.1 Boron<br>1.1.1 Arylboron Cross-Coupling Reactions<br>1.1.1.1 Arylboronic Acid Cross-Coupling Reactions<br>1.1.1.2 Arylboronic Acid Derivative Cross-Coupling Reactions<br>1.1.2 Hetarylboron Cross-Coupling Reactions<br>1.1.3 Alkenylboron Cross-Coupling Reactions<br>1.1.4 Alkylboron Cross-Coupling Reactions<br>1.1.5 Alkynyl- and Allylboron Cross-Coupling Reactions<br>1.2 Silicon<br>1.2.1 Arylsilicon Cross-Coupling Reactions<br>1.2.2 Hetarylsilicon Cross-Coupling Reactions<br>1.2.3 Alkenylsilicon Cross-Coupling Reactions<br>1.2.4 Alkylsilicon Cross-Coupling Reactions<br>1.2.5 Alkynyl- and Acylsilicon Cross-Coupling Reactions<br>1.3 Tin<br>1.3.1 Organotin Cross-Coupling Reactions<br>1.4 Zinc<br>1.4.1 Arylzinc Cross-Coupling Reactions<br>1.4.2 Hetarylzinc Cross-Coupling Reactions<br>1.4.3 Alkenylzinc Cross-Coupling Reactions<br>1.4.4 Alkylzinc Cross-Coupling Reactions<br>1.4.5 Alkynyl-, Benzyl-, and Propargylzinc Cross-Coupling Reactions<br>1.5 Magnesium<br>1.5.1 Aryl-, Hetaryl-, and Alkenylmagnesium Cross-Coupling Reactions<br>1.5.2 Alkyl- and Alkynylmagnesium Cross-Coupling Reactions</p>